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991.
High Energy Chemistry - Modification of Polyvinylidene fluoride (PVDF) by radiation grafting is a research hotspot in recent years. In this study, the monomer 2-Hydroxyethyl methacrylate (HEMA) was... 相似文献
992.
Dr. Bozheng Sun Dr. Meagan S. Oakley Dr. Kota Yoshida Yanwen Yang Prof. Matteo Tommasini Dr. Chiara Zanchi Dr. Andrea Lucotti Dr. Michael J. Ferguson Dr. Frank Hampel Prof. Mariusz Klobukowski Prof. Rik R. Tykwinski 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(38):e202200616
Cyclic tetraaryl[5]cumulenes ( 1 a–f ) have been synthesized and studied as a function of increasing ring strain. The magnitude of ring strain is approximated by the extent of bending of the cumulenic core as assessed by a combination of X-ray crystallographic analysis and DFT calculations. Trends are observed in 13C NMR, UV-vis, and Raman spectra associated with ring strain, but the effects are small. In particular, the experimental HOMO-LUMO gap is not appreciably affected by bending of the [5]cumulene framework from ca. 174° (λmax=504 nm) in 1 a to ca. 178° (λmax=494 nm) in 1 f . 相似文献
993.
Gromova M. A. Kharitonov Yu. V. Borisov S. A. Rybalova T. V. Tolstikova T. G. Shults E. E. 《Chemistry of Natural Compounds》2022,58(1):55-64
Chemistry of Natural Compounds - Synthetic methods were developed for isopimaric acid derivatives, the terminal carboxylic acid of which was separated by two or three methylenes from the tricyclic... 相似文献
994.
Romanenko G. V. Fokin S. V. Bogomyakov A. S. Zueva E. M. Ovcharenko V. I. 《Journal of Structural Chemistry》2022,63(3):441-450
Journal of Structural Chemistry - The structures of Ni(II), Cu(II), and Zn(II) complexes with anions of 2,5-pyrrolyl-disubstituted nitronyl nitroxide (L1) and iminonitroxide (L2) diradicals (HL1 is... 相似文献
995.
Vinod K. Ahirrao Rajiv A. Jadhav Suyog N. Vaidya Sachin S. Bhagwat Ravindra D. Yeole Mahesh V. Patel 《Biomedical chromatography : BMC》2022,36(6):e5354
Antibiotic susceptibility test (AST) discs are used as an in-vitro diagnostic tool to select the appropriate antibiotic to treat an infection. Generally, the concentration of the drug loaded on to the AST discs is measured by studying its activity against quality control organisms. This methodology has several limitations—it is time consuming, requires trained manpower, has a wider acceptance criteria of zone of inhibitions—causing ambiguity in judging smaller variations in drug concentration. To overcome these issues, we have developed and validated high-performance liquid chromatographic (HPLC) methods for the determination of strength of AST discs for in-house researched antibiotics, namely Levonadifloxacin/WCK 771, Nafithromycin/WCK 4873, Cefepime-Tazobactam/WCK 4282, and Cefepime-Zidebactam/WCK 5222. The drugs were extracted from the AST discs using an appropriate solvent. The developed methods are simple, accurate, precise, reproducible, rugged, and robust. They are efficient in terms of time, and can be easily conducted in a quality control laboratory during release as well as stability evaluation of AST disc. Application of HPLC methods for the determination of strength of AST discs ensures flawless quality and, consequently, a better selection of drugs to treat bacterial infections in clinics. 相似文献
996.
Magomedbekov U. G. Gasangadzhieva U. G. Etmisheva S. S. 《Moscow University Chemistry Bulletin》2022,77(4):197-201
Moscow University Chemistry Bulletin - The homogeneous process of cysteine oxidation in a stirred reactor is studied. We found that oscillatory mode can be realized in the cysteine–cobalt(II)... 相似文献
997.
Chromatographia - We developed a simple, rapid, ecological RP-HPLC method for the estimation of Pitavastatin (PIT), Fenofibrate (FEN), and their impurities in a novel fixed dose combination. We... 相似文献
998.
Chumakov Yu. M. Graur V. O. Ulchina Ya. I. Smaglii V. A. Gulea A. P. Garbuz O. S. Tsapkov V. I. 《Journal of Structural Chemistry》2022,63(6):905-913
Journal of Structural Chemistry - The crystal structures and biological properties of [N′-(2-oxidobenzylidene)-N-(prop-2-en-1-yl)-carbamohydrazonothioato(2-)](1,10-phenanthroline)copper... 相似文献
999.
Voronina Anna V. Bajtimirova Marina O. Semenishchev Vladimir S. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):913-920
Journal of Radioanalytical and Nuclear Chemistry - The effect of humic acids (HA) on 137Cs and 90Sr uptake by natural and modified aluminosilicates was studied under the conditions of radioactively... 相似文献
1000.
Dr. Emmanuelle Rémond Dr. Jean-Alain Fehrentz Laure Liénart Prof. Sébastien Clément Dr. Jean-Louis Banères Dr. Florine Cavelier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(47):e202201526
Synthesis of fluorescent P-hydroxybinaphtylphosphole-oxide or -sulfide was achieved by trapping a binaphtyl dianion with methyl dichlorophosphite or P-(N,N-diethylamino)dichlorophosphine, followed by oxidation or sulfuration of the P-center. After saponification or acid hydrolysis, the P-hydroxyphospholes were coupled to peptides using the coupling agent BOP, under the conditions required for the synthesis in solution or on a solid support. This new method was illustrated by the labeling of the JMV2959, a potent antagonist of the Growth Hormone Secretagogue Receptor type 1a (GHS−R1a). The labeled conjugates were used to characterize GHSR ligands by competition assays, based on Fluorescence Resonance Energy Transfer (FRET). Such P-hydroxyphosphole-oxide or -sulfide constitute a promising new class of compact fluorophores with large Stokes shift, for labeling biomolecules by grafting through the phosphorus atom. 相似文献